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Diffusion Equation

  Diffusion is an everyday experience; a hot cup of tea distributes its thermal energy or an uncorked perfume bottle distributes its scent throughout a room. Since nonunifrom distributions tend to distribute themselves in such a way as to produce uniformity, it is reasonable to assume that the flux density, J, is proportional to the concentration gradient. For a one- dimensional system we can write

 

where n is the density of the physical quantity of interest. The proportionality constant, K, is given various names depending on the quantity that n represents. It is called the thermal conductivity if n is heat and the coefficient of diffusion if n is molecular concentration. For the purposes of this discussion, we will consider to be a mass density along the x axis and we will refer to the integral of this function, , as the total mass.

The number of molecules between x and can be approximated by . If we assume that the total number of molecules is conserved (i.e., no source terms) then the number of molecules within the interval will change due to the fluxes at the two ends, x and .

The above equation is the differential form of the conservation of mass. A Taylor expansion about x of the last term allows the equation to be rewritten in the form

which can be combined with eq:Flux to produce the diffusion equation



Wolfgang Christian
Fri Apr 14 08:22:30 EDT 1995