Radial Wave Functions
The set of solutions to the radial equation can be found using
standard methods of differential equations. Notice that the radial solutions are determined by two quantum
numbers n and l. The solutions are the unnormalized associated
Laguerre polynomials.
Section 1 Exercises:
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Make a multiple plot of the possible radial wave functions for
n = 3. How is the behavior for l = 0 different than for l
= 1 or 2? Try this for a few other values for the principal
quantum number and see if your conclusion holds.
-
For n = 3, how many times does the radial wave
function cross zero (change signs) for each possible value of l?
Try this for a few other values for the principal quantum number and see if
you conclusion holds.
-
For a given principal quantum number, there is a maximum
value for l. The graph of the radial wave function in this case should
have only one maximum value. Obtain a general formula relating the
radius for this max value
for all n.
Note: Choosing the Show Multiple option and Resetting
allows up to 4 plots to be viewed simultaneously.
© 2000 by
Prentice-Hall, Inc. A Pearson Company